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- W2021643571 abstract "During the reaction of (o-lithiobenzyl)diphenylphosphine(I) with [NiCl2 · TMEDA], [PdCl2 · 2 Et2S] and [PtCl2 · 2 Et2S] the cyclometalated complexes II, III and IV, respectively, are formed. The Pd- and Pt-compounds appear as cis-trans isomers. The complex [p-C6H4CH2P(t-Bu)2PdCl]2 with I yields a mixed cyclometalated species in the cis form only. The reactions of I with copper and gold salts are also described. IR, NMR and mass spectra of these compounds are discussed. Im Verlauf der Umsetzung des (o-Lithiobenzyl)diphenylphosphins (I) mit [NiCl2 · TMEDA], [PdCl2 · 2 Et2S] und [PtCl2 · 2 Et2S] entstehen die cyclometallierten Komplexe II–IV, wobei die Pd- und Pt-Verbindungen als cis-trans Isomere auftreten. Mit [o-C6H4CH2P(t-Bu)2PdCl]2 liefert I eine gemischt cyclometalliert Spezies, die nur in der cis-Form entsteht. Darüber hinaus werden die Umsetzungen von I mit Kupfer- und Goldsalzen beschrieben. Die IR-, NMR- und Massenspektren dieser Verbindungen werden diskutiert." @default.
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- W2021643571 date "1978-04-01" @default.
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- W2021643571 title "Cyclometallierte komplexe des (o-lithiobenzyl)diphenylphosphins" @default.
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- W2021643571 doi "https://doi.org/10.1016/s0022-328x(00)94123-8" @default.
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