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- W2021647592 abstract "Abstract CO 2 adsorption with solid sorbents is one of the most promising options for post-combustion CO 2 capture strategies. Typical post-combustion flue-gas conditions are CO 2 1–15% vol. and atmospheric pressure and the performances of solid sorbents under typical flue gas conditions have been poorly investigated. In that condition the CO 2 uptake capacity is influenced primarily by material functionality effects rather than material pore metrics so materials with a distinctive surface chemistry (presence of activated surface atoms or sites) could find applications in adsorption technologies. Hence the sorbent selection became a key point because the materials should be convenient from the economic point of view but versatile in post-combustion conditions. Recent studies of CO 2 adsorption on low-cost iron metal oxide surfaces strongly encourage the possible use of metal oxide as sorbents, but the tendency of magnetite particles to agglomerate causes a lowering of CO 2 uptake capacity. The dispersion of magnetite nanoparticles on carbonaceous matrix appears to be a promising strategy to overcome this shortcoming. This work investigates the adsorption behavior of CO 2 on composite materials prepared coating a low-cost commercial carbon black (CB) with magnetite fine particles. The CO 2 capture capacity of composites produced at different CB load was evaluated on the basis of the breakthrough times measured at atmospheric pressure and room temperature in a lab-scale fixed bed micro-reactor. A CB–FM composite has been selected to verify the possibility of carrying out a two-stage operation and the thermochemical stability in a sound assisted fluidized bed. To this aim the reactor has been firstly operated for CO 2 adsorption and then for regeneration. The effect of multiple cycles of adsorption and desorption steps has been also quantified." @default.
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- W2021647592 date "2015-01-01" @default.
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- W2021647592 title "Magnetite loaded carbon fine particles as low-cost CO2 adsorbent in a sound assisted fluidized bed" @default.
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- W2021647592 doi "https://doi.org/10.1016/j.proci.2014.06.037" @default.
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