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- W2021670436 abstract "The surface oxidation behaviour of amorphous Ni64Zr36 and Ni91Zr9 was investigated in situ by XPS and UPS. Oxygen doses up to 2000 L (Langmuir units) were used to study the initial stages of oxidation of the clean surfaces in the temperature range from room temperature to 300°C. XPS core level binding energy shifts of Zr3d lines showed formation of zirconium oxides even at very low exposures. We observed different core level shifts of Zr3d in Ni64Zr36 and Ni91Zr9 indicating different stoichiometry of the oxides. A pronounced surface segregation of Zr was observed upon oxidation of the alloys. It is shown that this segregation is not a thermal but an oxygen induced phenomenon. The oxidation of Ni is strongly inhibited by Zr. Oxidation of Ni is only observed in Ni91Zr9 at 300°C after exposure to more than 1000 L O2. In the UPS spectra we found a shift of the Ni3d band position towards lower binding energy which can be interpreted as a subsurface Ni enrichment of the amorphous alloys." @default.
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- W2021670436 date "1989-07-01" @default.
- W2021670436 modified "2023-10-15" @default.
- W2021670436 title "Surface oxidation of amorphous NiZr alloys" @default.
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- W2021670436 doi "https://doi.org/10.1016/0169-4332(89)90495-9" @default.
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