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- W2021680498 abstract "Abstract By using a V-shaped N-containing ligand and a V-shaped carboxylate ligand, we have successfully synthesized a 3D novel copper homochiral coordination polymer, namely [Cu(OPY)(1,3-bdc)]n (complex 1), [1,3-H2bdc = isophthalic acid, OPY = 4,4′-(oxybis(4,1-phenylene))dipyridine]. The compound has been solvothermally synthesized and characterized by IR, elemental analysis, single crystal X-ray diffraction, XRD, UV–vis, and TG analysis. The complex 1 crystallizes in the chiral space group P65 and possesses an unprecedented uninodal 3D 75∙ 8 topology. However, the complex was synthesized by achiral materials. The complex 1 displays a moderate SHG response and its SHG efficiency is about 0.3 times that of urea. In addition, the compound shows high thermal stability." @default.
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- W2021680498 date "2014-07-01" @default.
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- W2021680498 title "A homochiral Cu(II) coordination polymer built from helical motif based on two V-shaped ligands" @default.
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- W2021680498 doi "https://doi.org/10.1016/j.inoche.2014.04.020" @default.
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