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• W2021683910 endingPage "1725" @default.
• W2021683910 startingPage "1717" @default.
• W2021683910 abstract "The discontinuous uptake and release of surfactants by hydrogels and the accompanying discontinuous volume transition is known to occur with a hysteresis. We have performed a theoretical analysis in order to find the mechanistic origin of this phenomenon. Using a mean-field model, we have quantitatively reproduced the experimental behavior by considering the cost of elastically deforming the gel material to allow phase coexistence. The major part of the hysteresis is due to the high phase coexistence cost of the swelling transition, since in this direction the coexistence cost depends not only on the elasticity of the network (being a weak force in comparison) but also on the entropy of the monovalent nonsurfactant electrolyte present in the system." @default.
• W2021683910 created "2016-06-24" @default.
• W2021683910 creator A5045876795 @default.
• W2021683910 creator A5088941318 @default.
• W2021683910 date "2015-01-17" @default.
• W2021683910 modified "2023-09-27" @default.
• W2021683910 title "Hysteresis in the Surfactant-Induced Volume Transition of Hydrogels" @default.
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• W2021683910 doi "https://doi.org/10.1021/jp5087416" @default.
• W2021683910 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25567724" @default.
• W2021683910 hasPublicationYear "2015" @default.
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