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- W2021690734 abstract "Abstract Here we report the synthesis and its characterization by X-ray diffraction, FTIR, UV–Vis and ESR spectroscopies, and magnetic measurements of a new compound: [Co2(NCO)4(DPDS)4]·3H2O (1) [DPDS = di(4-pyridyl)disulfide]. Single-crystal structure analysis reveals association of infinite linear cobalt(II) chains that are assembled in a pseudo 3D network through O–H(w)…O(NCO) and C–H(Py)…O(NCO) hydrogen bonds. The intermetallic M…M intrachain distances are 10.5 A and 10.3 A for Co(1) and Co(2), respectively. A canting phenomenon is observed for the compound associated to the non equivalence of the cobalt chains." @default.
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- W2021690734 date "2013-03-01" @default.
- W2021690734 modified "2023-10-08" @default.
- W2021690734 title "Spin canting in the [Co2(NCO)4(DPDS)4]·3H2O [DPDS=di(4-pyridyl)disulfide] coordination polymer" @default.
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- W2021690734 doi "https://doi.org/10.1016/j.poly.2012.06.023" @default.
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