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• W2021744076 abstract "The valence band evolution of ${mathrm{C}}_{60}$ film upon $mathrm{Yb}$ intercalation is investigated by the synchrotron radiation photoemission spectroscopy (SR-PES) technique. The results show that only ${mathrm{Yb}}_{2.75}{mathrm{C}}_{60}$ forms at lower intercalation stages and imply that other phases of ${mathrm{Yb}}_{x}{mathrm{C}}_{60}phantom{rule{0.3em}{0ex}}(x>2.75)$ form with more $mathrm{Yb}$ atoms intercalated into the ${mathrm{Yb}}_{2.75}{mathrm{C}}_{60}$ sample. No Fermi edge is observed for all the spectral lines in this work, which reveals that the superconducting $mathrm{Yb}$ fulleride, whether it is ${mathrm{Yb}}_{2.75}{mathrm{C}}_{60}$ or other phase, has semiconducting property at room temperature. To extract the intrinsic density of state of the valence band from the $mathrm{Yb}$ $4f$-superposed experimental data, the SR-PE spectra were measured for the well-defined phase of ${mathrm{Yb}}_{2.75}{mathrm{C}}_{60}$ with varying photon energies $(18.0--45.0phantom{rule{0.3em}{0ex}}mathrm{eV})$. The results show that the spectral data can drastically depart from the density of states of the valence band due to the photoemission of $mathrm{Yb}$ $4f$ core levels. However, the valence band can still be quantitatively extracted from the experimental data by the least-square simulation." @default.
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• W2021744076 date "2005-02-04" @default.
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• W2021744076 title "Synchrotron radiation photoemission study of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:mrow><mml:mi mathvariant=normal>Yb</mml:mi></mml:mrow></mml:mrow></mml:math>-intercalated<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:mrow><mml:msub><mml:mi mathvariant=normal>C</mml:mi><mml:mrow><mml:mn>60</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:mrow></mml:math>" @default.
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• W2021744076 doi "https://doi.org/10.1103/physrevb.71.085404" @default.
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