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- W2021745755 abstract "Abstract We report the synthesis of unidirectional light‐driven rotary molecular motors based on chiral overcrowded alkenes and their immobilisation on the surface of gold nanoparticles through two anchors. Using a combination of 1 H and 13 C NMR, UV/Vis and CD spectroscopy, we show that these motors preserve their photochemical and thermal behaviour after they have been attached to gold nanoparticles. Furthermore, we describe the synthesis of 2 H‐ and 13 C‐labelled derivatives that were used to verify the unidirectionality of the rotary cycle of these motors both in solution and while grafted to gold nanoparticles. Taken together, these data support the conclusion that these motors maintain their unidirectional rotary cycle when grafted to the surface of small (ca. 2 nm) gold nanoparticles. Thus, continuous irradiation of the system under appropriate conditions leads to unidirectional rotation of the upper half of the molecules relative to the entire nanoparticle." @default.
- W2021745755 created "2016-06-24" @default.
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- W2021745755 date "2008-12-12" @default.
- W2021745755 modified "2023-10-18" @default.
- W2021745755 title "Light-Driven Rotary Molecular Motors on Gold Nanoparticles" @default.
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- W2021745755 doi "https://doi.org/10.1002/chem.200800814" @default.
- W2021745755 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19009571" @default.
- W2021745755 hasPublicationYear "2008" @default.
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