FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2021749372> ?p ?o ?g. }

• W2021749372 endingPage "7971" @default.
• W2021749372 startingPage "7963" @default.
• W2021749372 abstract "A trace amount of alcohol cocatalyst and a stoichiometric amount of base are required during the hydrogenation of CO(2) to formic acid catalyzed by ruthenium trimethylphosphine complexes. Variation of the choice of alcohol and base causes wide variation in the rate of reaction. Acidic, nonbulky alcohols and triflic acid increase the rate of hydrogenation an order of magnitude above that which can be obtained with traditionally used methanol or water. Similarly, use of DBU rather than NEt(3) increases the rate of reaction by an order of magnitude. Turnover frequencies up to 95,000 h(-1) have now been obtained, and even higher rates should be possible using the cocatalyst and amine combinations identified herein. Preliminary in situ NMR spectroscopic observations are described, and the possible roles of the alcohol and base are discussed." @default.
• W2021749372 created "2016-06-24" @default.
• W2021749372 creator A5032910146 @default.
• W2021749372 creator A5044309195 @default.
• W2021749372 creator A5057730098 @default.
• W2021749372 creator A5063989231 @default.
• W2021749372 creator A5077461339 @default.
• W2021749372 date "2002-06-13" @default.
• W2021749372 modified "2023-10-16" @default.
• W2021749372 title "Hydrogenation of Carbon Dioxide Catalyzed by Ruthenium Trimethylphosphine Complexes: The Accelerating Effect of Certain Alcohols and Amines" @default.
• W2021749372 cites W1576189982 @default.
• W2021749372 cites W1973639779 @default.
• W2021749372 cites W1977730380 @default.
• W2021749372 cites W1993182381 @default.
• W2021749372 cites W1994733741 @default.
• W2021749372 cites W1997869189 @default.
• W2021749372 cites W2021795575 @default.
• W2021749372 cites W2023386159 @default.
• W2021749372 cites W2028257896 @default.
• W2021749372 cites W2038071113 @default.
• W2021749372 cites W2040506985 @default.
• W2021749372 cites W2045482669 @default.
• W2021749372 cites W2050035612 @default.
• W2021749372 cites W2056988912 @default.
• W2021749372 cites W2061521762 @default.
• W2021749372 cites W2074027401 @default.
• W2021749372 cites W2084442872 @default.
• W2021749372 cites W2092993934 @default.
• W2021749372 cites W2102144606 @default.
• W2021749372 cites W2108870766 @default.
• W2021749372 cites W2155604981 @default.
• W2021749372 cites W2314609016 @default.
• W2021749372 cites W2338104703 @default.
• W2021749372 cites W2949097019 @default.
• W2021749372 cites W2950511423 @default.
• W2021749372 cites W4244806755 @default.
• W2021749372 doi "https://doi.org/10.1021/ja0167856" @default.
• W2021749372 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/12095340" @default.
• W2021749372 hasPublicationYear "2002" @default.
• W2021749372 type Work @default.
• W2021749372 sameAs 2021749372 @default.
• W2021749372 citedByCount "301" @default.
• W2021749372 countsByYear W20217493722012 @default.
• W2021749372 countsByYear W20217493722013 @default.
• W2021749372 countsByYear W20217493722014 @default.
• W2021749372 countsByYear W20217493722015 @default.
• W2021749372 countsByYear W20217493722016 @default.
• W2021749372 countsByYear W20217493722017 @default.
• W2021749372 countsByYear W20217493722018 @default.
• W2021749372 countsByYear W20217493722019 @default.
• W2021749372 countsByYear W20217493722020 @default.
• W2021749372 countsByYear W20217493722021 @default.
• W2021749372 countsByYear W20217493722022 @default.
• W2021749372 countsByYear W20217493722023 @default.
• W2021749372 crossrefType "journal-article" @default.
• W2021749372 hasAuthorship W2021749372A5032910146 @default.
• W2021749372 hasAuthorship W2021749372A5044309195 @default.
• W2021749372 hasAuthorship W2021749372A5057730098 @default.
• W2021749372 hasAuthorship W2021749372A5063989231 @default.
• W2021749372 hasAuthorship W2021749372A5077461339 @default.
• W2021749372 hasConcept C131779359 @default.
• W2021749372 hasConcept C134306372 @default.
• W2021749372 hasConcept C144082473 @default.
• W2021749372 hasConcept C155647269 @default.
• W2021749372 hasConcept C161790260 @default.
• W2021749372 hasConcept C175113610 @default.
• W2021749372 hasConcept C178790620 @default.
• W2021749372 hasConcept C179104552 @default.
• W2021749372 hasConcept C185592680 @default.
• W2021749372 hasConcept C2775968720 @default.
• W2021749372 hasConcept C2777379063 @default.
• W2021749372 hasConcept C2779128551 @default.
• W2021749372 hasConcept C2779607525 @default.
• W2021749372 hasConcept C2779825165 @default.
• W2021749372 hasConcept C2781066024 @default.
• W2021749372 hasConcept C32909587 @default.
• W2021749372 hasConcept C33923547 @default.
• W2021749372 hasConcept C42058472 @default.
• W2021749372 hasConcept C555196967 @default.
• W2021749372 hasConcept C75473681 @default.
• W2021749372 hasConceptScore W2021749372C131779359 @default.
• W2021749372 hasConceptScore W2021749372C134306372 @default.
• W2021749372 hasConceptScore W2021749372C144082473 @default.
• W2021749372 hasConceptScore W2021749372C155647269 @default.
• W2021749372 hasConceptScore W2021749372C161790260 @default.
• W2021749372 hasConceptScore W2021749372C175113610 @default.
• W2021749372 hasConceptScore W2021749372C178790620 @default.
• W2021749372 hasConceptScore W2021749372C179104552 @default.
• W2021749372 hasConceptScore W2021749372C185592680 @default.
• W2021749372 hasConceptScore W2021749372C2775968720 @default.
• W2021749372 hasConceptScore W2021749372C2777379063 @default.
• W2021749372 hasConceptScore W2021749372C2779128551 @default.
• W2021749372 hasConceptScore W2021749372C2779607525 @default.
• W2021749372 hasConceptScore W2021749372C2779825165 @default.
• W2021749372 hasConceptScore W2021749372C2781066024 @default.
• W2021749372 hasConceptScore W2021749372C32909587 @default.
• W2021749372 hasConceptScore W2021749372C33923547 @default.
• W2021749372 hasConceptScore W2021749372C42058472 @default.

• next