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- W2021769055 abstract "Compounds were prepared of the general formula LnMX3 (where Ln = all rare earths or Bi, X = S, and M = Ta or Nb; Ln = La through Tb, X = S, and M = Ti or V; Ln = La through Gd, X = Se, and M = Ta or Nb; Ln = La, X = Se, and M = Ti or V). They were prepared by reaction of the elements in evacuated silica tubes with iodine as a mineralizing agent. They form as black shiny lamella crystals which exhibit plastic deformation, good thermal and hydrolytic stability, low coefficients of friction, and metallic conductivity. The crystal structures have subcells like PbNbS3 but the actual cells are larger and more complex. LaTiS3 is isotypic with LaCrS3." @default.
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- W2021769055 date "1975-01-01" @default.
- W2021769055 modified "2023-10-14" @default.
- W2021769055 title "Preparation and properties of LnMX3, where Ln = rare earths, Bi; M = Ta, Nb, Ti, V, and X = S, Se" @default.
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- W2021769055 doi "https://doi.org/10.1016/0022-4596(75)90181-4" @default.
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