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- W2021777013 abstract "The diffusion coefficients of C60 in dichloromethane and benzonitrile solutions containing 0.1 M tetrabutylammonium perchlorate were determined by single potential-step chronoamperometry at small disk electrodes. The diffusion coefficients of C60 were obtained by curve fitting of the chronoamperograms to a theoretical equation by Shoup and Szabo. The values were (1.4 ± 0.3)× 10–9 and (4.1 ± 0.3)× 10–10 m2 s–1, respectively (the errors are 95% confidence limits). The diffusion coefficients of C60– in these solutions were measured by double potential-step chronoamperometry. The ratios of the diffusion coefficients of C60 to those of C60– were obtained from theoretical curves of the ratios of the current at the second potential step to the current at the first one. The values of the ratios were 1.2 ± 0.2 and 1.0 ± 0.3, respectively." @default.
- W2021777013 created "2016-06-24" @default.
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- W2021777013 date "2006-07-01" @default.
- W2021777013 modified "2023-10-17" @default.
- W2021777013 title "Diffusion Coefficients of C60 and C60– in Benzonitrile and Dichloromethane Solutions Containing Tetrabutylammonium Perchlorate, Measured by Potential-step Chronoamperometry" @default.
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- W2021777013 doi "https://doi.org/10.2116/analsci.22.931" @default.
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