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• W2021781457 abstract "Total synthesis of the 18-membered ring cyclodepsipeptide believed to be respirantin (1b) has been achieved. The key step in the synthesis is an intramolecular transesterification of the β-ketoester alcohol 6 to afford the protected macrocycle 5. The synthetic product was shown to be identical to a natural product presumed to be respirantin (1b), and the absolute stereochemistry of six of the seven asymmetric centers of cyclodepsipeptide 1b was unequivocally established. Respirantin (1b) was found to be a remarkable inhibitor of cancer cell growth and related to the antimycin family of antibiotics." @default.
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• W2021781457 date "2007-07-01" @default.
• W2021781457 modified "2023-09-28" @default.
• W2021781457 title "Antineoplastic Agents. 561. Total Synthesis of Respirantin^1a" @default.
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• W2021781457 doi "https://doi.org/10.1021/np0680735" @default.
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