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- W2021796384 abstract "Coordination Chemistry of Perhalogenated Cyclopentadienes and Alkynes, X[1]. – Synthesis and Molecular Structure of a Cyclopentadienyl-1,3-dithiol π Complex, [C5Cl3(SH)2]Mn(CO)3 The reaction of [C5Cl4Li]Mn(CO)3 with elemental sulfur leads to [C5Cl4SLi]Mn(CO)3 (1), which is easily oxidized by air to the disulfide (OC)3Mn[C5Cl4S–SCl4C5]Mn(CO)3 (2). Addition of one equivalent of BuLi, followed by an excess of S8 produces the dithiolate [C5Cl3(SLi)2]Mn(CO)3 (3), which yields the dithiol [C5Cl3(SH)2]Mn(CO)3 (5) upon hydrolysis. The molecular structures of 2 and 5 have been determined by X-ray diffraction." @default.
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- W2021796384 title "Koordinationschemie perhalogenierter Cyclopentadiene und Alkine, X <sup>[1]</sup> Darstellung und Molekülstruktur eines Cyclopentadienyl‐1,3‐dithiol‐π‐Komplexes, [C <sub>5</sub> Cl <sub>3</sub> (SH) <sub>2</sub> ]Mn(CO) <sub>3</sub>" @default.
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- W2021796384 doi "https://doi.org/10.1002/cber.19921250715" @default.
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