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• W2021814503 abstract "We report a general preparation of heteroarylmethylzinc chlorides by direct zinc insertion into heteroarylmethyl chlorides, along with a facile and straightforward synthesis of these heterocyclic chloromethyl precursors. We demonstrate that heteroarylmethylzinc reagents undergo various reactions including cross-couplings, allylations, acylations, and addition reactions to aldehydes, leading to polyfunctional heterocyclic products. Furthermore, these heteroaromatic zinc compounds prove to be versatile reagents for the preparation of various N- and O-heterocycles and give access to an analogue of a CB1 modifier." @default.
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• W2021814503 date "2014-04-11" @default.
• W2021814503 modified "2023-10-17" @default.
• W2021814503 title "Preparation and Reactions of Heteroarylmethylzinc Reagents" @default.
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• W2021814503 doi "https://doi.org/10.1021/ol500790p" @default.
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