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- W2021828654 abstract "Abstract The binary manganese oxide, Mn 2 O 7 , is produced on prolonged broad-band UV—visible irradiation of Mn 2 (CO) 10 isolated in O 2 -doped argon matrices at 12 K. This is the first report of the production of a binary metal oxide containing two metal atoms by photolysis of a binuclear metal carbonyl in a matrix containing dioxygen. IR spectroscopic studies involving isotopic substitution with 18 O and intensity measurements confirm the O-bridged structure of this molecule and show that the MnOMn bond angle is about 150°." @default.
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- W2021828654 date "1988-02-01" @default.
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- W2021828654 title "Formation of dimanganese heptoxide, Mn2O7, by photolysis of Mn2(CO)10 in O2-doped argon matrices" @default.
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- W2021828654 doi "https://doi.org/10.1016/0022-2860(88)87014-5" @default.
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