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• W2021837146 abstract "The widespread presence and persistence of ethylenediaminetetraacetic acid (EDTA) in aquatic environments can lead to the formation of metal-EDTA complexes that influence metal bioavailability and mobility. Recently, the Hg(II)-EDTA complex was observed to slightly promote the biouptake of Hg(II) to the bacterium Escherichia coli and to undergo a relatively quick ligand exchange reaction with thiols at the bacterial cell membrane. The reactivity of a metal complex depends on its molecular structure; however, the molecular structure of aqueous Hg(II)-EDTA has yet to be reported. Here, we use X-ray absorption spectroscopy to determine the molecular structure of aqueous Hg(II)-EDTA. Our results suggest that aqueous Hg(II)-EDTA displays distorted octahedral geometry with one water molecule in the coordination sphere." @default.
• W2021837146 created "2016-06-24" @default.
• W2021837146 creator A5029995157 @default.
• W2021837146 creator A5083381371 @default.
• W2021837146 date "2015-03-13" @default.
• W2021837146 modified "2023-10-10" @default.
• W2021837146 title "The Molecular Structure of Aqueous Hg(II)-EDTA As Determined by X-ray Absorption Spectroscopy" @default.
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• W2021837146 doi "https://doi.org/10.1021/acs.jpca.5b00343" @default.
• W2021837146 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25746228" @default.
• W2021837146 hasPublicationYear "2015" @default.
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