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- W2021843487 abstract "A new complex of composition {[Co(L1)(N3)2]·ClO4}n (1) (L1=3,14-dimethyl-2,6,13,17-tetraazatricyclo[14.4.01.18.07.12]docosane) has been synthesized and structurally characterized by a combination of analytical, spectroscopic, and crystallographic methods. The cobalt(III) ion in 1 shows an octahedral geometry with four nitrogen atoms from the tetraaza macrocycle and two nitrogen atoms from the azide ligands. The [Co(L1)(N3)2]·ClO4 unit extends its structure to form the 1D polymer 1 through hydrogen bonding interactions among pre-organized N–H groups of the cobalt(III) macrocycle, azide ligands, and perchlorate anions." @default.
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- W2021843487 date "2003-03-01" @default.
- W2021843487 modified "2023-10-18" @default.
- W2021843487 title "An infinite 1D hydrogen-bonded polymer built from an azido cobalt(III) tetraaza macrocyclic complex" @default.
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- W2021843487 doi "https://doi.org/10.1016/s1387-7003(02)00753-0" @default.
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