Matches in SemOpenAlex for { <https://semopenalex.org/work/W2021844372> ?p ?o ?g. }
Showing items 1 to 91 of
91
with 100 items per page.
- W2021844372 endingPage "800" @default.
- W2021844372 startingPage "787" @default.
- W2021844372 abstract "The kinetic equations for an 81-reaction model of a photochemical smog chamber have been solved using a complete numerical integration as well as a quasi-steady-state approximation (QSSA) procedure. The two sets of results differ markedly in their prediction of experimentally significant factors such as the hydrocarbon depletion rate and the ozone and (NO)x peaking times. The sources of the discrepancy are traced to the fact that the assumed steady-state conditions were not satisfied, leading to errors in the concentrations of intermediate radicals which in turn affect critical rates in the reaction model. The occurrence of such discrepancies in various types of reaction models, and with different QSSA strategies, is discussed, and it is concluded that the extent of such errors in QSSA calculations cannot be reliably predicted. Their impact on conclusions regarding reaction mechanisms and rate constants can surpass uncertainties in experimental data; conversely the credibility of predictions derived through QSSA calculations becomes highly suspect. Since recently devloped methods for complete numerical integration of systems of kinetic equations are now available, it is recommended that these be adopted in future work, and that the use of QSSA be abandoned." @default.
- W2021844372 created "2016-06-24" @default.
- W2021844372 creator A5030993937 @default.
- W2021844372 creator A5039998441 @default.
- W2021844372 date "1974-11-01" @default.
- W2021844372 modified "2023-09-25" @default.
- W2021844372 title "The steady-state approximation: Fact or fiction?" @default.
- W2021844372 cites W2007741529 @default.
- W2021844372 cites W2058549619 @default.
- W2021844372 cites W2074404831 @default.
- W2021844372 cites W2074489186 @default.
- W2021844372 cites W2092168212 @default.
- W2021844372 cites W2141292391 @default.
- W2021844372 doi "https://doi.org/10.1002/kin.550060603" @default.
- W2021844372 hasPublicationYear "1974" @default.
- W2021844372 type Work @default.
- W2021844372 sameAs 2021844372 @default.
- W2021844372 citedByCount "49" @default.
- W2021844372 countsByYear W20218443722013 @default.
- W2021844372 countsByYear W20218443722014 @default.
- W2021844372 countsByYear W20218443722015 @default.
- W2021844372 countsByYear W20218443722016 @default.
- W2021844372 countsByYear W20218443722017 @default.
- W2021844372 countsByYear W20218443722020 @default.
- W2021844372 countsByYear W20218443722023 @default.
- W2021844372 crossrefType "journal-article" @default.
- W2021844372 hasAuthorship W2021844372A5030993937 @default.
- W2021844372 hasAuthorship W2021844372A5039998441 @default.
- W2021844372 hasConcept C121332964 @default.
- W2021844372 hasConcept C121864883 @default.
- W2021844372 hasConcept C135889238 @default.
- W2021844372 hasConcept C147789679 @default.
- W2021844372 hasConcept C148898269 @default.
- W2021844372 hasConcept C161790260 @default.
- W2021844372 hasConcept C175113610 @default.
- W2021844372 hasConcept C17744445 @default.
- W2021844372 hasConcept C185592680 @default.
- W2021844372 hasConcept C18762648 @default.
- W2021844372 hasConcept C187640670 @default.
- W2021844372 hasConcept C19262093 @default.
- W2021844372 hasConcept C199539241 @default.
- W2021844372 hasConcept C2780224610 @default.
- W2021844372 hasConcept C44870925 @default.
- W2021844372 hasConcept C55493867 @default.
- W2021844372 hasConcept C74650414 @default.
- W2021844372 hasConcept C8171440 @default.
- W2021844372 hasConcept C84999194 @default.
- W2021844372 hasConcept C93391505 @default.
- W2021844372 hasConcept C97355855 @default.
- W2021844372 hasConceptScore W2021844372C121332964 @default.
- W2021844372 hasConceptScore W2021844372C121864883 @default.
- W2021844372 hasConceptScore W2021844372C135889238 @default.
- W2021844372 hasConceptScore W2021844372C147789679 @default.
- W2021844372 hasConceptScore W2021844372C148898269 @default.
- W2021844372 hasConceptScore W2021844372C161790260 @default.
- W2021844372 hasConceptScore W2021844372C175113610 @default.
- W2021844372 hasConceptScore W2021844372C17744445 @default.
- W2021844372 hasConceptScore W2021844372C185592680 @default.
- W2021844372 hasConceptScore W2021844372C18762648 @default.
- W2021844372 hasConceptScore W2021844372C187640670 @default.
- W2021844372 hasConceptScore W2021844372C19262093 @default.
- W2021844372 hasConceptScore W2021844372C199539241 @default.
- W2021844372 hasConceptScore W2021844372C2780224610 @default.
- W2021844372 hasConceptScore W2021844372C44870925 @default.
- W2021844372 hasConceptScore W2021844372C55493867 @default.
- W2021844372 hasConceptScore W2021844372C74650414 @default.
- W2021844372 hasConceptScore W2021844372C8171440 @default.
- W2021844372 hasConceptScore W2021844372C84999194 @default.
- W2021844372 hasConceptScore W2021844372C93391505 @default.
- W2021844372 hasConceptScore W2021844372C97355855 @default.
- W2021844372 hasIssue "6" @default.
- W2021844372 hasLocation W20218443721 @default.
- W2021844372 hasOpenAccess W2021844372 @default.
- W2021844372 hasPrimaryLocation W20218443721 @default.
- W2021844372 hasRelatedWork W1965286643 @default.
- W2021844372 hasRelatedWork W2023289999 @default.
- W2021844372 hasRelatedWork W2031619525 @default.
- W2021844372 hasRelatedWork W2032151435 @default.
- W2021844372 hasRelatedWork W2037240858 @default.
- W2021844372 hasRelatedWork W2051133439 @default.
- W2021844372 hasRelatedWork W2082990203 @default.
- W2021844372 hasRelatedWork W2090443529 @default.
- W2021844372 hasRelatedWork W2143043153 @default.
- W2021844372 hasRelatedWork W4241395666 @default.
- W2021844372 hasVolume "6" @default.
- W2021844372 isParatext "false" @default.
- W2021844372 isRetracted "false" @default.
- W2021844372 magId "2021844372" @default.
- W2021844372 workType "article" @default.