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• W2021844998 abstract "The structure of a single polydiacetylene compound on a graphite substrate was investigated using atomic force microscopy (AFM). The linear conjugated polydiacetylenes were obtained through chain polymerization of a monomolecular layer of diacetylene compound on a graphite substrate under ultraviolet light irradiation. AFM observations revealed that the polydiacetylenes were imaged higher than the unpolymerized monomer rows. This result supports the ‘lifted-up’ conformation model, in which the polydiacetylene backbone is geometrically raised. To investigate why the polymer backbone is lifted, we also carried out first-principles density-functional calculations in the local density approximation. These calculations suggested that the steric hindrance between the alkyl side-chains of the monomers and the oligomer caused the lifted-up conformation." @default.
• W2021844998 created "2016-06-24" @default.
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• W2021844998 date "2008-01-01" @default.
• W2021844998 modified "2023-10-17" @default.
• W2021844998 title "Atomic force microscopy and theoretical investigation of the lifted-up conformation of polydiacetylene on a graphite substrate" @default.
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• W2021844998 doi "https://doi.org/10.1039/b718402f" @default.
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