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• W2021880900 abstract "The sodium amalgam reduction of the compound V(N-2,6-iPr2C6H3)Cl3(dme) in the presence of PMe3, under CO (2−3 atm), gives the complex V(N-2,6-iPr2C6H3)Cl(CO)2(PMe3)2 (1). Spectroscopic data for 1 suggest a trans, trans configuration of the CO and PMe3 ligands. Density functional theory (DFT) calculations were carried out in order to verify the proposed structure of 1. The adoption of the trans,trans geometry is preferred on the basis of steric arguments. DFT studies of the last steps in the reduction reaction that yields 1 also support the preferential formation of the trans,trans isomer." @default.
• W2021880900 created "2016-06-24" @default.
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• W2021880900 date "2000-01-04" @default.
• W2021880900 modified "2023-10-16" @default.
• W2021880900 title "MO Rationalization of the Synthesis and Structure of V(N-2,6-ⁱPr₂C₆H₃)Cl(CO)₂(PMe₃)₂ Complex" @default.
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• W2021880900 doi "https://doi.org/10.1021/om9905052" @default.
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