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- W2021915461 abstract "The nature of the quenching of the luminescent state of uranyl ion by a number of metal carbonyls, [M(CO)n], has been studied in aprotic solvents. Flash photolysis and e.s.r. and i.r. spectroscopy show that the quenching process takes place with concomitant formation of the paramagnetic reactive intermediate, [M(CO)n]+, and the [UO2]+ ion. The bimolecular quenching constants kQ are related to the free energy change of the electron-transfer process; thus values of log kQ are correlated with the oxidation potentials of [M(CO)n]. The primary photoproducts are involved subsequently in an irreversible redox process with formation of UIV and Mz+ ions." @default.
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- W2021915461 date "1979-01-01" @default.
- W2021915461 modified "2023-09-27" @default.
- W2021915461 title "Quenching of excited uranyl ion by metal carbonyls in aprotic solvents" @default.
- W2021915461 doi "https://doi.org/10.1039/dt9790000658" @default.
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