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- W2021966218 abstract "The chemistry of atomic iron reacting with cyclopropane in an argon matrix at 15 K has been investigated. A spontaneous reaction leads to the formation of C2H4FeCH2, [Fe(C2H2)][CH4], and a species in which FeH2 is complexed with allene, (FeH2)(H2CCCH2). UV photolysis of the matrix resulted in C−H bond activation to give methylvinyliron and ethynyliron hydride. Atomic iron was observed to form a weakly bound adduct with cyclopropane. This adduct is stable to irradiation using visible light, but UV photolysis led to enhanced absorptions assigned to methylvinyliron, ethynyliron hydride, and methane. A strongly interacting complex between two cyclopropane molecules and iron was observed. This species exhibits a large carbon−hydrogen frequency shift that is suggestive of an agostic hydrogen interaction. This complex undergoes a photoreaction at λ ≥ 500 nm to yield the disproportionation product Fe(C2H4)3, isolated for the first time in an argon matrix. Photolysis of Fe(C2H4)3 results in the loss of ethylene to form Fe(C2H4)2." @default.
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- W2021966218 date "1999-12-14" @default.
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- W2021966218 title "Matrix-Isolation Studies of the Reactions of Ground- and Excited-State Atomic Iron with Cyclopropane" @default.
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- W2021966218 doi "https://doi.org/10.1021/om990483j" @default.
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