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• W2021967211 abstract "Highly stereoselective metathesis reactions between optically active silyl compounds and copper(I) salts in 1,3-dimethyl-2-imidazolidinone (DMI) are reported. The substitution reaction of (+)-α-naphthylphenylmethylsilane with a mixture of lithium tert-butoxide and copper(I) salt smoothly proceeded in DMI to give the corresponding silyl ether with a high degree of retention of the configuration in a quantitative yield. The use of DMI as a solvent and the presence of a chloride ion are necessary for this reaction. An optically active alkynylsilane also reacted with the mixed reagent to afford the corresponding silyl ether. A mechanism of oxidative addition of the hydrosilane and reductive elimination of the silyl ether on copper is proposed." @default.
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• W2021967211 date "1999-02-01" @default.
• W2021967211 modified "2023-10-12" @default.
• W2021967211 title "Highly stereoselective metathesis reaction between optically active hydrosilane and copper(I) salt in 1,3-dimethyl-2-imidazolidinone" @default.
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• W2021967211 doi "https://doi.org/10.1016/s0022-328x(98)00923-1" @default.
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