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• W2021984633 endingPage "2854" @default.
• W2021984633 startingPage "2854" @default.
• W2021984633 abstract "Oxidative insertion of the In(I) 'carbene analogues', [In{N(Dipp)C(Me))2CH] (Ar = Dipp = 2,6-iPr2C6H3; Ar = Mes = 2,4,6-Me3C6H2) into the Fe-I bond of [CpFe(CO)2I] occurred cleanly and under mild conditions to yield the In(III) compounds [CH((CH3)2CN-2,6-iPr2C6H3)2In(I)FeCp(CO)2] and [CH( (CH3)2CN-2,4,6-Me3C6H3)2In(I)FeCp(CO)2], which have been fully characterised in solution and the solid state. Attempts to abstract the iodide anion from [CH( (CH3)2CN-2,6-iPr2C6H3)2In(I)FeCp(CO)2] to form cationic species containing a coordinated indium diyl were unsuccessful and resulted in a complex mixture of products from which two ionic species were isolated. Neither cation was found to contain indium by X-ray crystallographic analysis. These observations were indicative of ill-defined decomposition pathways as have been noted by previous workers. A further attempt to form a cationic iron species containing a coordinated [In(N(Dipp)C(Me) )2CH] fragment resulted in oxidation of the iron centre from Fe(II) to Fe(III), with deposition of indium metal, and the isolation of a cationic Fe(III) beta-diketiminate complex." @default.
• W2021984633 created "2016-06-24" @default.
• W2021984633 creator A5000195518 @default.
• W2021984633 creator A5078308385 @default.
• W2021984633 creator A5087546709 @default.
• W2021984633 date "2008-01-01" @default.
• W2021984633 modified "2023-10-18" @default.
• W2021984633 title "Organoiron compounds derived from the indium ‘carbene analogues’, [In{N(Ar)C(Me)}2CH] (Ar = dipp = 2,6-iPr2C6H3; = Mes = 2,4,6-Me3C6H2)" @default.
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• W2021984633 doi "https://doi.org/10.1039/b801160e" @default.
• W2021984633 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18478148" @default.
• W2021984633 hasPublicationYear "2008" @default.
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