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• W2022007197 endingPage "4276" @default.
• W2022007197 startingPage "4262" @default.
• W2022007197 abstract "Reaction of PNPCo, where PNP is (tBu2PCH2SiMe2)2N-, with the persistent radical galvinoxyl, G, gives PNPCoIIG, a nonplanar S = 3/2 species. Reaction with PhCH2Cl or with 0.5 mol I2 gives PNPCoX (X = Cl or I, respectively), but additional I2, seeking CoIII, gives instead oxidation at phosphorus: (tBu2P(I)CH2SiMe2NSiMe2CH2PtBu2)CoI2. Hydrogen-atom transfer reagents fail to give PNPCoH, but H2 gives instead PNPCo(H)2, a result rationalized thermodynamically based on DFT calculations. Multiple equiv of PhSiH3 give a product of Co(V), where N/SiPh and P/Si bonds have formed. N2CH(SiMe3) gives a 1:1 adduct of PNPCo, whose metric parameters suggest partial oxidation above CoI; N2CHPh gives a 1:1 adduct but with very different spectroscopic features. PhN3 reacts fast, via several intermediates detected below 0 degrees C, to finally release N2 and form a CoI product where one phosphorus has been oxidized, PN(P=NPh)Co. Whereas PNPCo(N3) resists loss of N2 on heating, one electron oxidation gives a rapid loss of N2, and the remaining nitride nitrogen is quickly incorporated into the chelate ligand, giving [tBu2PCH2SiMe2NSiMe2NP(tBu2)=CH2Co]. O2 or PhI=O generally gives products where one or both phosphorus centers are converted to its oxide, bonded to cobalt." @default.
• W2022007197 created "2016-06-24" @default.
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• W2022007197 creator A5081854327 @default.
• W2022007197 date "2008-03-11" @default.
• W2022007197 modified "2023-10-11" @default.
• W2022007197 title "Redox Chemistry of the Triplet Complex (PNP)Co^I" @default.
• W2022007197 cites W1525392772 @default.
• W2022007197 cites W1963681117 @default.
• W2022007197 cites W1966051519 @default.
• W2022007197 cites W1966804020 @default.
• W2022007197 cites W1968191262 @default.
• W2022007197 cites W1977679669 @default.
• W2022007197 cites W1978243262 @default.
• W2022007197 cites W1979303449 @default.
• W2022007197 cites W1981257757 @default.
• W2022007197 cites W1983372190 @default.
• W2022007197 cites W1984605747 @default.
• W2022007197 cites W1992501619 @default.
• W2022007197 cites W1992522832 @default.
• W2022007197 cites W1993308327 @default.
• W2022007197 cites W1993505425 @default.
• W2022007197 cites W2000110019 @default.
• W2022007197 cites W2001144156 @default.
• W2022007197 cites W2003134478 @default.
• W2022007197 cites W2007381493 @default.
• W2022007197 cites W2009911625 @default.
• W2022007197 cites W2010396430 @default.
• W2022007197 cites W2011890891 @default.
• W2022007197 cites W2013963010 @default.
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• W2022007197 cites W2019459605 @default.
• W2022007197 cites W2019688607 @default.
• W2022007197 cites W2020268013 @default.
• W2022007197 cites W2021056015 @default.
• W2022007197 cites W2021394397 @default.
• W2022007197 cites W2022403881 @default.
• W2022007197 cites W2032225219 @default.
• W2022007197 cites W2034034877 @default.
• W2022007197 cites W2037232670 @default.
• W2022007197 cites W2037827010 @default.
• W2022007197 cites W2040569466 @default.
• W2022007197 cites W2043510643 @default.
• W2022007197 cites W2045984931 @default.
• W2022007197 cites W2046520758 @default.
• W2022007197 cites W2051575056 @default.
• W2022007197 cites W2056778024 @default.
• W2022007197 cites W2066360040 @default.
• W2022007197 cites W2075778667 @default.
• W2022007197 cites W2076469261 @default.
• W2022007197 cites W2076486952 @default.
• W2022007197 cites W2082063105 @default.
• W2022007197 cites W2085697630 @default.
• W2022007197 cites W2085977660 @default.
• W2022007197 cites W2087593458 @default.
• W2022007197 cites W2088268670 @default.
• W2022007197 cites W2091501139 @default.
• W2022007197 cites W2092267450 @default.
• W2022007197 cites W2093979766 @default.
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• W2022007197 cites W2106434300 @default.
• W2022007197 cites W2137805202 @default.
• W2022007197 cites W2161256103 @default.
• W2022007197 cites W2164588275 @default.
• W2022007197 cites W2170588477 @default.
• W2022007197 cites W2949627759 @default.
• W2022007197 cites W2951651346 @default.
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• W2022007197 doi "https://doi.org/10.1021/ja074378+" @default.
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