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- W2022008498 abstract "Nitromethane, as probe molecule, and infrared spectroscopy, as analytical tool, were used to characterize the basic properties of alkali-exchanged X zeolites and metal oxides. It was observed that this probe molecule could adsorb molecularly, dissociatively and dissociative-associatively, according to the basic strength of the sites present on the studied solids. Alkali-exchanged X zeolites presented weak basic sites and a scale of basicity could be established, CsX > KX >NaX > LiX, based on the shift of the CH3 rock angular bending frequency. On Al2O3, ZrO2, TiO2 weak and intermediate basic sites were identified, while on MgO, La2O3 and alkali-promoted MgO just strong basic sites were found. For the alkali-promoted MgO samples no basicity scale could be observed. For the universe of the studied materials nitromethane behaves as a proper probe molecule to characterize basic sites with different strengths." @default.
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- W2022008498 date "2010-09-01" @default.
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- W2022008498 title "Infrared spectroscopic characterization of basic properties: Nitromethane as probe molecule" @default.
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- W2022008498 doi "https://doi.org/10.1016/j.molcata.2010.07.005" @default.
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