FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022012134> ?p ?o ?g. }

• W2022012134 endingPage "234" @default.
• W2022012134 startingPage "223" @default.
• W2022012134 abstract "Several novel Pd(II), Pt(II) and Pt(IV) dimers containing 1,2-bis(diphenylphosphino)acetylene (dppa) as bridging ligand have been prepared and characterized by X-ray diffraction methods, NMR spectroscopy (195Pt{1H}, 31P{H1H}), IR spectroscopy, elemental analyses and melting points. The X-ray structures of the former reported complexes [Pd2Cl4(dppa)2] (1) and [Pt2Cl4(dppa)2] (2) are given for the first time: 1: monoclinic, P21/n, a =14.401(3), b = 12.100(2), c = 15.880(3) Å, β = 91.36(3)°, Z = 2, R = 0.039 for 6432 observed reflections (1>3σ(1)); 2: orthorhombic, Pbcn, a = 13.995(3), b = 17.669(4), c== 21.960(4) Å, Z = 4, R = 0.052 for 2332 observed reflections (1>3σ(1)). These two X-ray structures are discussed with respect to the former given ambiguous interpretation of the X-ray structure of [PtPdCl4(dppa)2]. Replacement of the chlorides in 1 or 2 by iodides leads to [Pd2I4(dppa)2] (3) or [Pt2I4(dppa)2] (4). 4 is also fully characterized by an X-ray structure analysis for the first time: 4: monoclinic, P21/c, a = 10.586(2), b = 30.526(6), c = 18.383(4) Å, β = 100.09(3)°, Z = 4, R = 0.061 for 4698 observed reflections (1>3σ(1)). The X-ray structures of 1,2 and 4 reveal different orientations of the dppa bridges due to metal-phosphorus dπ-dπ back bonding leading to different angles between the square-planar coordination units, respectively. Replacement of the chlorides in 1 by NO2− leads to [Pd2(NO2)4(dppa)2] (5), whereas in 2 only one chloride can be substituted by NO2− and [Pt2Cl3(NO2) (dppa)2] (6) is formed. A similar reaction of 2 with 2,2′-bipyridine (bipy) produces [Pt2Cl2(dppa)2(bipy)](BF4)2 (7). Oxidation of 2 by chlorine gives the Pt(IV) dimer [Pt2Cl8(dppa)2] (8). An equimolar amount of PdCl2 reacts with one triple bond of 2 leading to [Pt2PdCl6(dppa)2] (9). an analogous manner [Pd4Cl8(dppa)2] (10) is formed from 1 and two equimolar amounts of PdCl2. The stability and reactivity of complexes 1–10 are discussed with respect to the X-ray structures of 1,2,4 and [PtPdCl4(dppa)2]." @default.
• W2022012134 created "2016-06-24" @default.
• W2022012134 creator A5001287899 @default.
• W2022012134 creator A5030937222 @default.
• W2022012134 creator A5073192599 @default.
• W2022012134 creator A5091453305 @default.
• W2022012134 date "1997-03-01" @default.
• W2022012134 modified "2023-10-18" @default.
• W2022012134 title "Binuclear palladium(II), platinum(II) and platinum(IV) complexes containing 1,2-bis (diphenylphosphino)acetylene: different orientations of the diphosphine-bridges due to metal-phosphorus dπ-dπ back bonding" @default.
• W2022012134 cites W1565810868 @default.
• W2022012134 cites W1968809952 @default.
• W2022012134 cites W1969441906 @default.
• W2022012134 cites W1972436826 @default.
• W2022012134 cites W1979535105 @default.
• W2022012134 cites W1980880855 @default.
• W2022012134 cites W1983016278 @default.
• W2022012134 cites W1988995943 @default.
• W2022012134 cites W1992576083 @default.
• W2022012134 cites W1992722453 @default.
• W2022012134 cites W1995880239 @default.
• W2022012134 cites W1997199881 @default.
• W2022012134 cites W2001707947 @default.
• W2022012134 cites W2002554407 @default.
• W2022012134 cites W2004998318 @default.
• W2022012134 cites W2006854225 @default.
• W2022012134 cites W2007261603 @default.
• W2022012134 cites W2007558408 @default.
• W2022012134 cites W2013787938 @default.
• W2022012134 cites W2016795341 @default.
• W2022012134 cites W2017396767 @default.
• W2022012134 cites W2024969328 @default.
• W2022012134 cites W2026999832 @default.
• W2022012134 cites W2030246629 @default.
• W2022012134 cites W2041833669 @default.
• W2022012134 cites W2047752283 @default.
• W2022012134 cites W2049285936 @default.
• W2022012134 cites W2049894339 @default.
• W2022012134 cites W2052571553 @default.
• W2022012134 cites W2053062710 @default.
• W2022012134 cites W2053521775 @default.
• W2022012134 cites W2059401704 @default.
• W2022012134 cites W2062609480 @default.
• W2022012134 cites W2071111058 @default.
• W2022012134 cites W2073826667 @default.
• W2022012134 cites W2077766366 @default.
• W2022012134 cites W2088471479 @default.
• W2022012134 cites W2090411888 @default.
• W2022012134 cites W2110552395 @default.
• W2022012134 cites W2274435861 @default.
• W2022012134 cites W2950407765 @default.
• W2022012134 cites W2951641387 @default.
• W2022012134 doi "https://doi.org/10.1016/s0020-1693(96)05449-7" @default.
• W2022012134 hasPublicationYear "1997" @default.
• W2022012134 type Work @default.
• W2022012134 sameAs 2022012134 @default.
• W2022012134 citedByCount "31" @default.
• W2022012134 countsByYear W20220121342012 @default.
• W2022012134 countsByYear W20220121342014 @default.
• W2022012134 countsByYear W20220121342015 @default.
• W2022012134 countsByYear W20220121342016 @default.
• W2022012134 countsByYear W20220121342018 @default.
• W2022012134 countsByYear W20220121342019 @default.
• W2022012134 crossrefType "journal-article" @default.
• W2022012134 hasAuthorship W2022012134A5001287899 @default.
• W2022012134 hasAuthorship W2022012134A5030937222 @default.
• W2022012134 hasAuthorship W2022012134A5073192599 @default.
• W2022012134 hasAuthorship W2022012134A5091453305 @default.
• W2022012134 hasConcept C115624301 @default.
• W2022012134 hasConcept C116569031 @default.
• W2022012134 hasConcept C120665830 @default.
• W2022012134 hasConcept C121332964 @default.
• W2022012134 hasConcept C161790260 @default.
• W2022012134 hasConcept C170493617 @default.
• W2022012134 hasConcept C178790620 @default.
• W2022012134 hasConcept C185592680 @default.
• W2022012134 hasConcept C207114421 @default.
• W2022012134 hasConcept C2777517455 @default.
• W2022012134 hasConcept C37243968 @default.
• W2022012134 hasConcept C502130503 @default.
• W2022012134 hasConcept C50515024 @default.
• W2022012134 hasConcept C518104683 @default.
• W2022012134 hasConcept C544153396 @default.
• W2022012134 hasConcept C55493867 @default.
• W2022012134 hasConcept C61276311 @default.
• W2022012134 hasConcept C71240020 @default.
• W2022012134 hasConcept C8010536 @default.
• W2022012134 hasConceptScore W2022012134C115624301 @default.
• W2022012134 hasConceptScore W2022012134C116569031 @default.
• W2022012134 hasConceptScore W2022012134C120665830 @default.
• W2022012134 hasConceptScore W2022012134C121332964 @default.
• W2022012134 hasConceptScore W2022012134C161790260 @default.
• W2022012134 hasConceptScore W2022012134C170493617 @default.
• W2022012134 hasConceptScore W2022012134C178790620 @default.
• W2022012134 hasConceptScore W2022012134C185592680 @default.
• W2022012134 hasConceptScore W2022012134C207114421 @default.
• W2022012134 hasConceptScore W2022012134C2777517455 @default.
• W2022012134 hasConceptScore W2022012134C37243968 @default.
• W2022012134 hasConceptScore W2022012134C502130503 @default.

• next