FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022012139> ?p ?o ?g. }

• W2022012139 endingPage "1131" @default.
• W2022012139 startingPage "1119" @default.
• W2022012139 abstract "New square-pyramidal bis(ene-1,2-dithiolate)MoSe complexes, [MoIVSe(L)2]2−, have been synthesised along with their terminal sulfido analogues, [MoIVS(L)2]2−, using alkyl (LC4H8), phenyl (LPh) and methyl carboxylate (LCOOMe) substituted dithiolene ligands (L). These complexes now complete three sets of MoIVO, MoIVS and MoIVSe species that are coordinated with identical ene-1,2-dithiolate ligands. The [alkyl substituted Mo(S/Se)(LC4H8)2]2− complexes were reported in prior investigations (H. Sugimoto, T. Sakurai, H. Miyake, K. Tanaka and H. Tsukube, Inorg. Chem. 2005, 44, 6927, H. Tano, R. Tajima, H. Miyake, S. Itoh and H. Sugimoto, Inorg. Chem. 2008, 47, 7465). The new series of complexes enable a systematic investigation of terminal chalcogenido and supporting ene-1,2-dithiolate ligand effects on geometric structure, electronic structure, and spectroscopic properties. X-ray crystallographic analysis of these (Et4N)2[MoEL2] (E = terminal chalocogenide) complexes reveals an isostructural Mo centre that adopts a distorted square pyramidal geometry. The ME bond distances observed in the crystal structures and the ν(ME) vibrational frequencies indicate that these bonds are weakened with an increase in L→Mo electron donation (LCOOMe < LPh < LC4H8), and this order is confirmed by an electrochemical study of the complexes. The 77Se NMR resonances in MoSeL complexes appear at lower magnetic fields as the selenido ion became less basic from MoSeLC4H8, MoSeLPh and MoSeLCOOMe. Electronic absorption and resonance Raman spectroscopies have been used to assign key ligand-field, MLCT, LMCT and intraligand CT bands in complexes that possess the LCOOMe ligand. The presence of low-energy intraligand CT transition in these MoELCOOMe compounds directly probes the electron withdrawing nature of the -COOMe substituents, and this underscores the complex electronic structure of square pyramidal bis(ene-1,2-dithiolate)-MoIV complexes that possess extended dithiolene conjugation." @default.
• W2022012139 created "2016-06-24" @default.
• W2022012139 creator A5001884632 @default.
• W2022012139 creator A5026745464 @default.
• W2022012139 creator A5036731820 @default.
• W2022012139 creator A5039985062 @default.
• W2022012139 creator A5041954417 @default.
• W2022012139 creator A5044362708 @default.
• W2022012139 creator A5046395364 @default.
• W2022012139 creator A5067712894 @default.
• W2022012139 date "2011-01-01" @default.
• W2022012139 modified "2023-09-30" @default.
• W2022012139 title "Chalcogenidobis(ene-1,2-dithiolate)molybdenum(<scp>iv</scp>) complexes (chalcogenide E = O, S, Se): Probing MoE and ene-1,2-dithiolate substituent effects on geometric and electronic structure" @default.
• W2022012139 cites W1491668995 @default.
• W2022012139 cites W1967238575 @default.
• W2022012139 cites W1967552832 @default.
• W2022012139 cites W1969078948 @default.
• W2022012139 cites W1970326168 @default.
• W2022012139 cites W1973658255 @default.
• W2022012139 cites W1977583441 @default.
• W2022012139 cites W1984160524 @default.
• W2022012139 cites W1989169111 @default.
• W2022012139 cites W1998377216 @default.
• W2022012139 cites W2000646783 @default.
• W2022012139 cites W2006243394 @default.
• W2022012139 cites W2011281931 @default.
• W2022012139 cites W2019526975 @default.
• W2022012139 cites W2023854972 @default.
• W2022012139 cites W2025927160 @default.
• W2022012139 cites W2029292244 @default.
• W2022012139 cites W2044465745 @default.
• W2022012139 cites W2045926261 @default.
• W2022012139 cites W2046081922 @default.
• W2022012139 cites W2047276432 @default.
• W2022012139 cites W2048642998 @default.
• W2022012139 cites W2052103874 @default.
• W2022012139 cites W2054646026 @default.
• W2022012139 cites W2062193741 @default.
• W2022012139 cites W2064012830 @default.
• W2022012139 cites W2066370105 @default.
• W2022012139 cites W2068520544 @default.
• W2022012139 cites W2071308893 @default.
• W2022012139 cites W2074156707 @default.
• W2022012139 cites W2084031367 @default.
• W2022012139 cites W2084422184 @default.
• W2022012139 cites W2086022136 @default.
• W2022012139 cites W2089570924 @default.
• W2022012139 cites W2106824077 @default.
• W2022012139 cites W3005075392 @default.
• W2022012139 cites W4245399940 @default.
• W2022012139 doi "https://doi.org/10.1039/c0dt00871k" @default.
• W2022012139 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3168557" @default.
• W2022012139 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21165484" @default.
• W2022012139 hasPublicationYear "2011" @default.
• W2022012139 type Work @default.
• W2022012139 sameAs 2022012139 @default.
• W2022012139 citedByCount "11" @default.
• W2022012139 countsByYear W20220121392012 @default.
• W2022012139 countsByYear W20220121392013 @default.
• W2022012139 countsByYear W20220121392015 @default.
• W2022012139 countsByYear W20220121392017 @default.
• W2022012139 countsByYear W20220121392018 @default.
• W2022012139 countsByYear W20220121392019 @default.
• W2022012139 countsByYear W20220121392021 @default.
• W2022012139 countsByYear W20220121392022 @default.
• W2022012139 crossrefType "journal-article" @default.
• W2022012139 hasAuthorship W2022012139A5001884632 @default.
• W2022012139 hasAuthorship W2022012139A5026745464 @default.
• W2022012139 hasAuthorship W2022012139A5036731820 @default.
• W2022012139 hasAuthorship W2022012139A5039985062 @default.
• W2022012139 hasAuthorship W2022012139A5041954417 @default.
• W2022012139 hasAuthorship W2022012139A5044362708 @default.
• W2022012139 hasAuthorship W2022012139A5046395364 @default.
• W2022012139 hasAuthorship W2022012139A5067712894 @default.
• W2022012139 hasBestOaLocation W20220121392 @default.
• W2022012139 hasConcept C115624301 @default.
• W2022012139 hasConcept C116569031 @default.
• W2022012139 hasConcept C120665830 @default.
• W2022012139 hasConcept C121332964 @default.
• W2022012139 hasConcept C170493617 @default.
• W2022012139 hasConcept C178790620 @default.
• W2022012139 hasConcept C185592680 @default.
• W2022012139 hasConcept C205188671 @default.
• W2022012139 hasConcept C27777614 @default.
• W2022012139 hasConcept C2778689049 @default.
• W2022012139 hasConcept C2780263894 @default.
• W2022012139 hasConcept C40003534 @default.
• W2022012139 hasConcept C55493867 @default.
• W2022012139 hasConcept C71240020 @default.
• W2022012139 hasConcept C8010536 @default.
• W2022012139 hasConcept C92840921 @default.
• W2022012139 hasConceptScore W2022012139C115624301 @default.
• W2022012139 hasConceptScore W2022012139C116569031 @default.
• W2022012139 hasConceptScore W2022012139C120665830 @default.
• W2022012139 hasConceptScore W2022012139C121332964 @default.
• W2022012139 hasConceptScore W2022012139C170493617 @default.
• W2022012139 hasConceptScore W2022012139C178790620 @default.
• W2022012139 hasConceptScore W2022012139C185592680 @default.

• next