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- W2022022904 abstract "A theory for adiabatic electron-transfer reactions at metal electrodes is presented. The model Hamiltonian is similar to that of the Levich and Dogonadze theory for non-adiabatic reactions, but the rate is not calculated from perturbation theory but by techniques familiar from the Anderson-Newns model for adsorption. In the limit of comparatively weak interactions, this model reduces to the Marcus theory: for stronger interactions there are significant deviations. A possible classification of electrochemical electron-transfer reactions is discussed." @default.
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- W2022022904 date "1986-06-01" @default.
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- W2022022904 title "A theory of adiabatic electron-transfer reactions" @default.
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- W2022022904 doi "https://doi.org/10.1016/0022-0728(86)80505-8" @default.
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