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• W2022030922 abstract "Abstract Association constants for the interaction of almost insoluble substrates with triphenylene ketal‐based receptors in toluene have been determined by means of an extraction method employing the corresponding radio‐labelled substrates. Flexible and more polar receptors tend to aggregate and exhibit inferior extraction qualities. Binding constants in toluene were found to be in the range 10 5 –10 7 m −1 , which is significantly higher than in dichloromethane. X‐ray analyses indicate the direct participation of a water molecule in the binding process, which may account for the surprisingly small effect of moisture in the solvent on the stability of the complexes." @default.
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• W2022030922 date "2007-04-19" @default.
• W2022030922 modified "2023-10-17" @default.
• W2022030922 title "Extraction of Radio-Labelled Xanthine Derivatives by Artificial Receptors: Deep Insight into the Association Behaviour" @default.
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• W2022030922 doi "https://doi.org/10.1002/chem.200601231" @default.
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