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- W2022035827 abstract "The X-ray structure of a 1:1 Cu/O(2) adduct revealed side-on (eta(2)) O(2) coordination. Density functional calculations corroborated the structure, indicated a significant contribution of a Cu(III)-(O(2)(2-)) resonance form, and provided insights into the key bonding interactions. Reaction of a 1:1 adduct supported by a slightly different beta-diketiminate ligand with Cu(I) reagents resulted in the formation of novel asymmetric bis(mu-oxo) complexes that were identified by EPR, UV-vis, and Raman spectroscopy, as well as by an X-ray structure in one instance." @default.
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- W2022035827 date "2002-08-16" @default.
- W2022035827 modified "2023-10-10" @default.
- W2022035827 title "Snapshots of Dioxygen Activation by Copper: The Structure of a 1:1 Cu/O<sub>2</sub> Adduct and Its Use in Syntheses of Asymmetric Bis(μ-oxo) Complexes" @default.
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- W2022035827 doi "https://doi.org/10.1021/ja027164v" @default.
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