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- W2022036002 abstract "Steady state photolysis of Os(OEP)[P(OMe)3]2, where OEP is octaethylporphine, in the chlorinated solvents CH2Cl2, CHCl3 and CCl4 at 365 and 405 nm and at 22 °C results in the formation of an osmium(IV) porphyrin identified as Os(OEP)Cl2. The reaction is described as an oxidative substitution reaction. The rate of formation of the photolysis product increases as the solvent varies in the order CH2Cl2 < CHCl3 < CCl4 (in the ratio 1:8:120). The quantum yield of product formation is 0.004 and 1.4 in CH2Cl2 and CCl4 respectively. A possible mechanism involving radicals is suggested and is discussed in terms of the experimental observations." @default.
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- W2022036002 date "1981-01-01" @default.
- W2022036002 modified "2023-09-23" @default.
- W2022036002 title "Oxidative substitution reaction of the osmochrome Os(OEP)[P(OMe)3]2 in chlorinated solvents" @default.
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- W2022036002 doi "https://doi.org/10.1016/0047-2670(81)80003-2" @default.
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