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- W2022045605 startingPage "10674" @default.
- W2022045605 abstract "We discuss, for the d and f transition metals, the competition between atomiclike electrostatic Coulomb and exchange interactions and loss of atomic characteristics in the solid through screening of f and d charge fluctuations and hybridization. We derive semiempirical relations describing these interactions for the 3d, 4d, 5d, 4f, and 5f elements in the environment of a metallic host. We then compare these to the hybridization widths, also semiempirically determined, and arrive at conclusions concerning the localization of the d or f electrons and the formation of magnetic moments. We show that some of the light actinides can exhibit negative ${U}^{mathrm{eff}}$ behavior dependent on their valence in the solid. We argue that some d transition metals may belong to the same group if properly alloyed." @default.
- W2022045605 created "2016-06-24" @default.
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- W2022045605 date "1988-06-15" @default.
- W2022045605 modified "2023-10-16" @default.
- W2022045605 title "Electron-electron interaction and localization in<i>d</i>and<i>f</i>transition metals" @default.
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- W2022045605 doi "https://doi.org/10.1103/physrevb.37.10674" @default.
- W2022045605 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/9944521" @default.
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