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- W2022045765 abstract "Recently, Limbach, Hennig, and Stulz reported the IR measurement of NH/ND stretching vibration in free-base tetraphenylporphine. The observation of narrow bandwidth in IR spectra lead them to conclude that the inner protons migrate without substantial coupling to the motion of skeleton. In this Comment, it is pointed out that the bandwidth in IR spectra is not relevant to the proton-skeleton coupling problem in the proton migration process, and some controversies on the mechanism of proton migration are discussed." @default.
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- W2022045765 title "Comment on ‘‘IR-spectroscopic study of isotope effects on the NH/ND stretching bands of meso-tetraphenylporphine and vibrational hydrogen tunneling’’" @default.
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- W2022045765 doi "https://doi.org/10.1063/1.446568" @default.
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