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- W2022048552 abstract "Protease catalysed hydrolysis of N-Boc-amino acid esters allows us to obtain N-Boc l-acids and d-esters of amino butanoic acid, nor-leucine, nor-valine, leucine and t-leucine in excellent ee. The reaction occurs in short reaction times and high concentrations. When a biphasic system (buffer–MTBE) is employed, a strong solvent effect is observed. This method could be of significance for the preparation of d-t-leucine, for which a practical method is currently unavailable." @default.
- W2022048552 created "2016-06-24" @default.
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- W2022048552 date "2006-08-01" @default.
- W2022048552 modified "2023-09-28" @default.
- W2022048552 title "Enzymatic approach to both enantiomers of N-Boc hydrophobic amino acids" @default.
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- W2022048552 doi "https://doi.org/10.1016/j.tetasy.2006.07.012" @default.
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