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- W2022048564 abstract "The new compounds Nd3NbO4Cl6 and Ln3NbO5XCl3 have been prepared. Nd3NbO4Cl6 was prepared by reacting NdCl3, NdOCl, and Nb2O5 (3:3:1) in evacuated, sealed silica ampoules (850°C, 48 hr). It is isostructural with Pr3NbO4Cl6 and crystallizes in the hexagonal space group P63m (Nr. 176) with cell dimensions a = 12.724(2)Å, c = 3,932(1)Å(powder data). New representatives of a group of isostructural compounds of formula Ln3MO5XCl3 (Ln =LaNd or Th, U; M =Nb, Ta, W, U6+; X =OH, F, O) could be obtained by firing stoichiometric quantities of oxides, oxyhalides, and chlorides in silica ampoules. They also crystallize in the hexagonal space group P63m. The cell dimensions were obtained with a Guinier camera." @default.
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- W2022048564 date "1992-08-01" @default.
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- W2022048564 title "Neue Oxochloroniobate der Seltenen Erden" @default.
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- W2022048564 doi "https://doi.org/10.1016/0022-4596(92)90309-j" @default.
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