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- W2022055216 abstract "The pimaricin-inducing (PI) factor, produced by Streptomyces natalensis is a proposed pheromone with a peculiar vicinal diamine structure. The first synthesis of this molecule is reported. It features oxidative dimerization of an aci-nitro anion derived from tris(hydroxymethyl)nitromethane and disproportionation catalyst-facilitated hydrogenation of the resulting vicinal tertiary dinitro compound. As the synthesis requires only four steps with no chromatographic separations, it provides a convenient route to prepare PI factor for biological studies and industrial applications." @default.
- W2022055216 created "2016-06-24" @default.
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- W2022055216 date "2010-07-15" @default.
- W2022055216 modified "2023-10-14" @default.
- W2022055216 title "Efficient Synthesis of a Peculiar Vicinal Diamine Semiochemical from <i>Streptomyces natalensis</i>" @default.
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- W2022055216 doi "https://doi.org/10.1021/ol1013763" @default.
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