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- W2022055976 abstract "The polymerization of methyl methacrylate and various acrylates initiated by ester enolates in the presence of cesium halide−trialkylaluminum complexes, Cs[AlnR2nX] (n = 1, 2; R = Et, Bui), in toluene has living and controlled character at −20 °C for methacrylates (X = Cl) and at −65 °C for n-butyl acrylate (X = F). Quantitative monomer conversions are usually reached, leading to polymers with narrow molecular weight distributions (Mw/Mn < 1.1). Kinetic investigations indicate a rather complex polymerization mechanism, and we assume an equilibrium between at least two active species. With this new initiating system, beside acrylate homopolymers, random and graft copolymers can be synthesized." @default.
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- W2022055976 date "2001-02-14" @default.
- W2022055976 modified "2023-10-16" @default.
- W2022055976 title "Anionic Polymerization of (Meth)acrylates in the Presence of Cesium Halide−Trialkylaluminum Complexes in Toluene" @default.
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- W2022055976 doi "https://doi.org/10.1021/ma9916640" @default.
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