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• W2022058489 abstract "Iridium complex anions (IrX62-, IrX5-, IrX4-, K+·IrX62- X = Cl, Br, and K+·IrCl52-) were subjected to high-energy collisions with Cs atoms in an accelerator mass spectrometer. The experiments probed the complex anions’ propensity for electron attachment, which was only observed for IrCl5-, IrBr5- and K+·IrCl52-. These observations indicate that electron transfer is controlled by the relative stability of the Ir oxidation state and the availability of low-lying unoccupied molecular orbitals. Formation of IrX52- is notable since these ions are amongst the smallest molecular dianions observed in the gas-phase, while the K+·IrCl53- complex contains the smallest experimentally observed trianion." @default.
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• W2022058489 date "2007-07-01" @default.
• W2022058489 modified "2023-10-16" @default.
• W2022058489 title "On the propensity for electron transfer in high-energy collisions of iridium complex anions with cesium atoms" @default.
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• W2022058489 doi "https://doi.org/10.1016/j.cplett.2007.05.081" @default.
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