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- W2022059654 abstract "The are spectrum of bismuth was investigated in three orders of the best 30-foot Chicago grating. The light source consisted of a heated quartz tube containing bismuth metal, filled with a few mm of helium and excited by a 4-meter oscillator. At a sufficiently high vapor pressure of bismuth only the are spectrum is excited and is so intense, that not only almost all previously known lines but also many new lines were studied. Because of the very high quality of the grating and the sharpness of the lines, pictures were obtained which show in the third order an exceptionally high resolution of about 400,000, which constitutes the highest resolving power ever obtained with a diffraction grating. The results of measurements of the hyperfine structures for 55 lines are presented in Tables I and IV; the wave-lengths for the components corresponding to the transitions between hyperfine structure levels with highest $F$ quantum numbers, and the exact term values for the atomic energy levels derived from them are collected in Tables II and IV. Many new levels were identified; the total number of known levels is increased from 27 to 45. Hyperfine structure separations of levels are given in Tables II, III, and IV; all values previously reported by Zeeman, Back, and Goudsmit for 13 atomic levels were corrected and separations for 28 more levels were determined." @default.
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- W2022059654 date "1942-12-01" @default.
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- W2022059654 title "Arc Spectrum of Bismuth Bi I" @default.
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- W2022059654 doi "https://doi.org/10.1103/physrev.62.526" @default.
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