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- W2022065143 endingPage "1116" @default.
- W2022065143 startingPage "1095" @default.
- W2022065143 abstract "Abstract The first asymmetric Carroll rearrangement opens up an efficient access to highly functionalised ketones 4 and 7 with vicinal quaternary and tertiary stereogenic centres of excellent diastereo‐ and enantiomeric purity ( de =89–96%, ee =82 to >98%) by using the SAMP/RAMP hydrazone methodology. Starting from hydrazones ( S )‐ 2 , we describe a dianionic and a Lewis acid‐mediated variant of the [3.3]‐sigmatropic Carroll rearrangement. The relative and absolute configuration of the new stereogenic centres created by C–C bond formation were assigned by X‐ray crystallographic analysis of the hydrazones 3h and 3j ." @default.
- W2022065143 created "2016-06-24" @default.
- W2022065143 creator A5056620790 @default.
- W2022065143 creator A5075289770 @default.
- W2022065143 creator A5080612612 @default.
- W2022065143 creator A5088754757 @default.
- W2022065143 date "1996-07-01" @default.
- W2022065143 modified "2023-10-17" @default.
- W2022065143 title "The First Asymmetric Carroll Rearrangement Diastereo‐ and Enantioselective Synthesis of Polyfunctional Ketones with Vicinal Quaternary and Tertiary Stereogenic Centers" @default.
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