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- W2022066716 abstract "A series of donor−π-acceptor dyes based on rigid ladder-type pentaphenylene spacers 1–3 have been synthesized from dibromopentaphenylene 4 in three steps. The three dyes contain the same acceptors (2-cyanoacrylic acid) as anchor groups but differ in donor units (diphenylamino 1, phenothiazinyl 2, and bis(N,N-4-dimethylaminophenyl)amino 3). Their maximum absorption peaks range from 442 to 457 nm with high extinction coefficients, while dye 3 shows a broader absorption band in the visible region along with a weak NIR absorption band due to the formation of amino radical cation. The DSSCs based on these dyes demonstrate the highest IPCE value of 73% and power conversion efficiency of 2.3% (liquid cell) and 0.8% (solid cell), respectively. Although the power conversion efficiencies are not so high, this work explores new donor−spacer−acceptor models and the effects of molecular design on photophysical and photoelectrochemical properties." @default.
- W2022066716 created "2016-06-24" @default.
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- W2022066716 date "2008-02-19" @default.
- W2022066716 modified "2023-09-23" @default.
- W2022066716 title "Ladder-Type Pentaphenylene Dyes for Dye-Sensitized Solar Cells" @default.
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- W2022066716 doi "https://doi.org/10.1021/cm703459p" @default.
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