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• W2022072461 abstract "The crystal structure of [NH3(CH2)6NH3]BiCl5 was determined at: 223 K [P212121 (Z=4), a=7.788(1), b=13.886(2), c=13.972(2) Å], 308 K [P21/n (Z=8), a=19.972(3), b=7.772(2), c=20.166(3) Å, β=92.32(1)°] and 378 K [Pnma (Z=4), a=13911(2), b=7.834(7), c=14.457(2) Å]. It was consisted of isolated (BiCl52−)n anionic chains composed by distorted octahedra BiCl63− sharing two corners and +NH3(CH2)6NH3+ cations placed in the free cavities between anionic chains. In the β phase, there are two crystallographically inequivalent cations and two one-dimensional anionic chains (BiCl52−)n in which BiCl63− octahedra was doubly tilted and simply tilted. Two structural phase transitions at low and high temperatures α (P212121, 223 K)↔β (P21/n, 308 K)↔γ (Pnma, 373 K) are observed and discussed. It was crystallographically showed that both anionic and cationic entities contribute to phase transitions mechanisms. The BiCl63− octahedra were found to posses significant distortions on decreasing temperature and became more distorted in α (223 K) phase. It is argued that these deformations are caused by weak to moderate NH···Cl hydrogen bonding." @default.
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• W2022072461 date "2013-04-01" @default.
• W2022072461 modified "2023-10-16" @default.
• W2022072461 title "Structures and phases transition in hexylenediammonium pentachlorobismuthate (III) [NH3(CH2)6NH3]BiCl5 crystal" @default.
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• W2022072461 doi "https://doi.org/10.1016/j.jssc.2013.01.002" @default.
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