Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022073414> ?p ?o ?g. }
Showing items 1 to 64 of
64
with 100 items per page.
- W2022073414 endingPage "136" @default.
- W2022073414 startingPage "129" @default.
- W2022073414 abstract "The silacyclobutanes CH 2 CH 2 CH 2 S iClX ( 2 ), X=Cl, and ( 3 ), X=Me, are attacked by the oxyl (CF 3 ) 2 NO· ( 1 ) at the 3-position leading to the monosubstituted products (CF 3 ) 2 NO CHCH 2 SiClXC H 2 ( 8 ), X = Cl, and ( 9 ), X = Me, and a minor amount of the disubstituted product (CF 3 ) 2 NO CHCH 2 SiMeClC HON(CF 3 ) 2 ( 10 ) which arises via the silacyclobutene CH 2 CH=CHS iMeCl ( 17 ). With the disilacyclobutane CH 2 SiMe 2 CH 2 S iMe 2 ( 4 ), the only silicon-containing products isolated are (CF 3 ) 2 NOSiMe 2 CH 2 SiMe 2 F ( 13 ) and FsiMe 2 CH 2 SiMe 2 F ( 12 ), which are formed via attack of oxyl 1 at a ring CH 2 group. The 1-substituted 1-silacyclobutanes CH 2 CH 2 CH 2 S iRR 1 ( 28 ), R=Cl, R 1 =ON(CF 3 ) 2 ( 29 ), R=R 1 =ON(CF 3 ) 2 , and ( 27 ), R=Me, R 1 =ON(CF 3 ) 2 , are conveniently prepared by reaction of the mercurial [(CF 3 ) 2 NO] 2 Hg ( 26 ) with the silacyclobutanes 2 and 3 . Reaction of the 3-substituted silacyclobutane 9 with anhydrous hydrogen chloride gives the open-chain, substituted dialkyldichlorosilane (CF 3 ) 2 NOCHMeCH 2 SiMeCl 2 ( 14 ), while treatment with hydrochloric acid affords a low molecular weight polysiloxane ( 15 ) derived from dichlorosilane 14 ." @default.
- W2022073414 created "2016-06-24" @default.
- W2022073414 creator A5024659579 @default.
- W2022073414 creator A5068512448 @default.
- W2022073414 date "1994-05-01" @default.
- W2022073414 modified "2023-09-27" @default.
- W2022073414 title "The synthesis of [bis(trifluoromethyl)amino-oxy]silacyclobutanes" @default.
- W2022073414 cites W2029614861 @default.
- W2022073414 cites W2086563840 @default.
- W2022073414 cites W2323658320 @default.
- W2022073414 cites W2331710848 @default.
- W2022073414 doi "https://doi.org/10.1016/0022-1139(93)02941-7" @default.
- W2022073414 hasPublicationYear "1994" @default.
- W2022073414 type Work @default.
- W2022073414 sameAs 2022073414 @default.
- W2022073414 citedByCount "4" @default.
- W2022073414 crossrefType "journal-article" @default.
- W2022073414 hasAuthorship W2022073414A5024659579 @default.
- W2022073414 hasAuthorship W2022073414A5068512448 @default.
- W2022073414 hasConcept C155647269 @default.
- W2022073414 hasConcept C178790620 @default.
- W2022073414 hasConcept C185592680 @default.
- W2022073414 hasConcept C187714232 @default.
- W2022073414 hasConcept C2776442012 @default.
- W2022073414 hasConcept C2778695967 @default.
- W2022073414 hasConcept C2779523567 @default.
- W2022073414 hasConcept C2780263894 @default.
- W2022073414 hasConcept C2780378348 @default.
- W2022073414 hasConcept C2781087020 @default.
- W2022073414 hasConcept C544956773 @default.
- W2022073414 hasConcept C71240020 @default.
- W2022073414 hasConceptScore W2022073414C155647269 @default.
- W2022073414 hasConceptScore W2022073414C178790620 @default.
- W2022073414 hasConceptScore W2022073414C185592680 @default.
- W2022073414 hasConceptScore W2022073414C187714232 @default.
- W2022073414 hasConceptScore W2022073414C2776442012 @default.
- W2022073414 hasConceptScore W2022073414C2778695967 @default.
- W2022073414 hasConceptScore W2022073414C2779523567 @default.
- W2022073414 hasConceptScore W2022073414C2780263894 @default.
- W2022073414 hasConceptScore W2022073414C2780378348 @default.
- W2022073414 hasConceptScore W2022073414C2781087020 @default.
- W2022073414 hasConceptScore W2022073414C544956773 @default.
- W2022073414 hasConceptScore W2022073414C71240020 @default.
- W2022073414 hasIssue "2" @default.
- W2022073414 hasLocation W20220734141 @default.
- W2022073414 hasOpenAccess W2022073414 @default.
- W2022073414 hasPrimaryLocation W20220734141 @default.
- W2022073414 hasRelatedWork W2022073414 @default.
- W2022073414 hasRelatedWork W2344022560 @default.
- W2022073414 hasRelatedWork W2911842645 @default.
- W2022073414 hasRelatedWork W2951458519 @default.
- W2022073414 hasRelatedWork W2953348506 @default.
- W2022073414 hasRelatedWork W2953358060 @default.
- W2022073414 hasRelatedWork W3010212107 @default.
- W2022073414 hasRelatedWork W3015795223 @default.
- W2022073414 hasRelatedWork W4233655858 @default.
- W2022073414 hasRelatedWork W4248019927 @default.
- W2022073414 hasVolume "67" @default.
- W2022073414 isParatext "false" @default.
- W2022073414 isRetracted "false" @default.
- W2022073414 magId "2022073414" @default.
- W2022073414 workType "article" @default.