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- W2022076477 abstract "Q2[MoIVO{1,2-S2-3,6-(Ph3CCONH)2C6H2}2] (Q = NEt4 (1), PPh4 (2)) was synthesized and characterized as a model for Mo-enzymes. The crystal structure of 2 shows the slightly distorted square pyramidal core, MoIVOS4. The O-atom transfer reaction from Me3NO to Me3N in the presence of 1 proceeds at 30 to 48 times higher rates than in the presence of [MoIVO{1,2-S2-(C6H4)}2]2− (3)." @default.
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- W2022076477 date "2005-01-01" @default.
- W2022076477 modified "2023-09-26" @default.
- W2022076477 title "Monooxomolybdenum(IV) Complex with Extremely Bulky Dithiolate Ligands — Acceleration of O-atom Transfer by Distorted Square Pyramidal Conformation" @default.
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- W2022076477 doi "https://doi.org/10.1246/cl.2005.44" @default.
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