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- W2022076858 abstract "Abstract The first systematic survey of the BaOReRe2O7 phase diagram is reported, with emphasis on the reduced ternary oxides. At 800°C, the previously reported compounds Ba3Re2O9, Ba2ReO5, and Ba3ReO6 were observed, all of which contain Re(VI) in ReO6 octahedra. The stability of these phases is apparently due to ReO π-bonding in and between the octahedra. The previously unknown structure of Ba2ReO5 was determined by powder neutron diffraction and found to be isotypic with that of K2VO2F3 (space group Pnma), with a = 7.3233(2), b = 5.7745(1), and c = 11.4124(2), A. ReO6 octahedra share adjacent corners to produce cis chains which are held together by 10 coordinated Ba atoms." @default.
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- W2022076858 date "1987-11-01" @default.
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- W2022076858 title "An investigation of the low oxidation state chemistry of rhenium in the BaOReRe2O7 phase diagram" @default.
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- W2022076858 doi "https://doi.org/10.1016/0022-4596(87)90142-3" @default.
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