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- W2022077665 abstract "Abstract The kinetics of the oxidation of a series of benzoins (BH2) by octacyanomolybdate(V) (OX3−), in a buffered alkaline aqueous methanolic medium, have been studied spectrophotometrically. The experimental results are in agreement with the following rate law: − 1 2 d[OX3−]/dt = k[OX3−][BH2][OH−], and the following order of reactivity was observed: o,o′-dichloro- > p,p′-dichloro- > m,m′-dimethoxybenzoin > benzoin > p,p′-dimethoxy- > o,o′-dimethoxybenzoin. The rate measurements were used to calculate the thermodynamic activation parameters ΔG‡, ΔH‡ and ΔS‡. The relative rates correlate very well with the Hammett substituent constants and support a negatively-charged intermediate. The effect of substituents correlated with a p-value of 1.36." @default.
- W2022077665 created "2016-06-24" @default.
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- W2022077665 date "1990-01-01" @default.
- W2022077665 modified "2023-09-27" @default.
- W2022077665 title "Substituent effects on the oxidation of benzoins by the octacyanomolybdate(V) ion" @default.
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