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• W2022082781 startingPage "10254" @default.
• W2022082781 abstract "A series of pyrene-labeled dendrimers were prepared from generation n = 1 to n = 4 where the pyrenes were attached to the end groups of the dendrimers. Pyrene excimer formation was monitored by steady-state and time-resolved fluorescence spectroscopy as a function of generation number and in terms of the IE/IM ratio and the average rate constant of excimer formation <k>. To account for the unconventional distribution of pyrene labels which were neither randomly distributed throughout the macromolecule nor limited to just two units which are the only two pyrene-labeling schemes that can be dealt with in a straightforward manner, a Model Free (MF) analysis was applied to the global analysis of the fluorescence decays. Within experimental error, the IE/IM ratios and <k> obtained from, respectively, the steady-state fluorescence spectra and the time-resolved fluorescence decays were found to increase linearly with increasing generation number. This result is inconsistent with the fact that both the IE/IM ratio and <k> are proportional to the local concentration of pyrene inside the dendrimer ([Py]loc) which is not expected to increase with generation number if the excited pyrene is assumed to diffuse freely throughout the dendrimer interior. Since the core-dense model predicts that the dendrimer terminal ends can occupy any position throughout the dendrimer interior, these results suggest that excimer formation between the pyrene-labeled ends is enhanced due to the branched nature of the dendrimer." @default.
• W2022082781 created "2016-06-24" @default.
• W2022082781 creator A5044926783 @default.
• W2022082781 creator A5077414330 @default.
• W2022082781 creator A5078957584 @default.
• W2022082781 creator A5085165441 @default.
• W2022082781 date "2010-07-27" @default.
• W2022082781 modified "2023-10-16" @default.
• W2022082781 title "A Study of the Dynamics of the Branch Ends of a Series of Pyrene-Labeled Dendrimers Based on Pyrene Excimer Formation" @default.
• W2022082781 cites W1516240693 @default.
• W2022082781 cites W1968798927 @default.
• W2022082781 cites W1978253805 @default.
• W2022082781 cites W1979367981 @default.
• W2022082781 cites W1981358456 @default.
• W2022082781 cites W1982485380 @default.
• W2022082781 cites W1983508666 @default.
• W2022082781 cites W1984076871 @default.
• W2022082781 cites W1986635559 @default.
• W2022082781 cites W1989086045 @default.
• W2022082781 cites W1989208181 @default.
• W2022082781 cites W1992620470 @default.
• W2022082781 cites W1992779470 @default.
• W2022082781 cites W1992999827 @default.
• W2022082781 cites W1994063476 @default.
• W2022082781 cites W1997364649 @default.
• W2022082781 cites W1998676149 @default.
• W2022082781 cites W2000831543 @default.
• W2022082781 cites W2001190765 @default.
• W2022082781 cites W2004875122 @default.
• W2022082781 cites W2004954979 @default.
• W2022082781 cites W2005806059 @default.
• W2022082781 cites W2007189194 @default.
• W2022082781 cites W2007669812 @default.
• W2022082781 cites W2009500363 @default.
• W2022082781 cites W2009770736 @default.
• W2022082781 cites W2010730493 @default.
• W2022082781 cites W2012643870 @default.
• W2022082781 cites W2013059533 @default.
• W2022082781 cites W2013544484 @default.
• W2022082781 cites W2014254822 @default.
• W2022082781 cites W2021975722 @default.
• W2022082781 cites W2022548846 @default.
• W2022082781 cites W2024141686 @default.
• W2022082781 cites W2025014632 @default.
• W2022082781 cites W2025662628 @default.
• W2022082781 cites W2030424674 @default.
• W2022082781 cites W2030979932 @default.
• W2022082781 cites W2031455432 @default.
• W2022082781 cites W2033654339 @default.
• W2022082781 cites W2035821461 @default.
• W2022082781 cites W2036707124 @default.
• W2022082781 cites W2042869626 @default.
• W2022082781 cites W2043471441 @default.
• W2022082781 cites W2047928731 @default.
• W2022082781 cites W2048008624 @default.
• W2022082781 cites W2048545066 @default.
• W2022082781 cites W2049723495 @default.
• W2022082781 cites W2052553494 @default.
• W2022082781 cites W2055972988 @default.
• W2022082781 cites W2056508068 @default.
• W2022082781 cites W2059883645 @default.
• W2022082781 cites W2061066443 @default.
• W2022082781 cites W2065556904 @default.
• W2022082781 cites W2069443907 @default.
• W2022082781 cites W2069534884 @default.
• W2022082781 cites W2070291888 @default.
• W2022082781 cites W2075544487 @default.
• W2022082781 cites W2076639509 @default.
• W2022082781 cites W2077456968 @default.
• W2022082781 cites W2080671657 @default.
• W2022082781 cites W2085635195 @default.
• W2022082781 cites W2087586730 @default.
• W2022082781 cites W2088273616 @default.
• W2022082781 cites W2090135401 @default.
• W2022082781 cites W2093554913 @default.
• W2022082781 cites W2118195840 @default.
• W2022082781 cites W2131342299 @default.
• W2022082781 cites W2141530525 @default.
• W2022082781 cites W2141856711 @default.
• W2022082781 cites W2144574425 @default.
• W2022082781 cites W2144985364 @default.
• W2022082781 cites W2151827636 @default.
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• W2022082781 cites W3099020906 @default.
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• W2022082781 doi "https://doi.org/10.1021/jp9102228" @default.
• W2022082781 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20701362" @default.
• W2022082781 hasPublicationYear "2010" @default.
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