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- W2022084174 abstract "1,4-Diphenylbutin-1,4-dion (1) addiert die Isocyanide 2 im Sinne einer “Criss-Cross”-Cycloaddition zu den 1H,4H-Furo[3,4-c]furanen 3, deren Konstitution und Konfiguration durch eine Röntgenstrukturanalyse von 3a sowie durch IR-, MS- und 13C-NMR-Daten gesichert sind. Durch Hydrolyse von 3a wird ein Furanring geöffnet, was zum Furan-3-carbonsäuretoluidid 4 führt. Synthesis of 1H, 4H-Furo[3,4-c]furans via “Criss-cross” Cycloaddition Reaction of Isocyanides to 1,4-Diphenylbutine-1,4-dione 1,4-Diphenylbutine-1,4-dione (1) adds the isocyanides 2 via a “criss-cross” cycloaddition reaction yielding the 1H,4H-furo[3,4-c]furans 3, the constitution and configuration of which could be confirmed by an X-ray analysis of 3a and by IR, MS, and 13C NMR data. Hydrolysis of 3a opens one of the furan rings leading to the toluidide 4 of a furan-3-carboxylic acid." @default.
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- W2022084174 date "1983-04-15" @default.
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- W2022084174 title "1H, 4H-Furo[3,4-c]furane durch “Criss-Cross”-Cycloaddition von Isocyaniden an 1,4-Diphenylbutin-1,4-dion" @default.
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- W2022084174 doi "https://doi.org/10.1002/jlac.198319830412" @default.
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