FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022088554> ?p ?o ?g. }

• W2022088554 endingPage "1588" @default.
• W2022088554 startingPage "1561" @default.
• W2022088554 abstract "Characteristic fragmentation processes of aliphatic sulphoxides and sulphones such as loss of hydroxyl, ‘alkene’ and/or ‘alkenyl’ are associated with hydrogen migrations to oxygen. A study of the mass spectra of di-n-butyl sulphoxide and sulphone, the saturated five-, six- and seven-membered ring sulphoxides and sulphones and their site-specifically deuterated analogues shows that these hydrogen migrations are nonspecific. Apparently steric factors play an important role in determining the relative contributions of initial hydrogen transfer from the various positions. The sites of abstraction probably determine the extent of competition between consecutive or concerted loss of hydroxyl, carbon-sulphur fission or other processes (e.g. McLafferty rearrangement). Apart from the McLafferty rearrangement only the loss of hydroxyl from sulphones shows a strong dependence on the site of initial hydrogen abstraction: γ-hydrogen is lost preferentially, yielding a cyclized [M  OH] ion." @default.
• W2022088554 created "2016-06-24" @default.
• W2022088554 creator A5000698290 @default.
• W2022088554 creator A5035049323 @default.
• W2022088554 date "1970-12-01" @default.
• W2022088554 modified "2023-10-18" @default.
• W2022088554 title "The mass spectra of some aliphatic and alicyclic sulphoxides and sulphones" @default.
• W2022088554 cites W1534368140 @default.
• W2022088554 cites W1564498867 @default.
• W2022088554 cites W1969276533 @default.
• W2022088554 cites W1973967405 @default.
• W2022088554 cites W1986202674 @default.
• W2022088554 cites W2004263223 @default.
• W2022088554 cites W2011405300 @default.
• W2022088554 cites W2021995704 @default.
• W2022088554 cites W2031929374 @default.
• W2022088554 cites W2047685672 @default.
• W2022088554 cites W2048813773 @default.
• W2022088554 cites W2067681155 @default.
• W2022088554 cites W2068745903 @default.
• W2022088554 cites W2315760029 @default.
• W2022088554 cites W2316950350 @default.
• W2022088554 cites W2317109829 @default.
• W2022088554 cites W2329662090 @default.
• W2022088554 cites W2332067779 @default.
• W2022088554 cites W2335135183 @default.
• W2022088554 cites W2335356612 @default.
• W2022088554 cites W4236505637 @default.
• W2022088554 doi "https://doi.org/10.1002/oms.1210031214" @default.
• W2022088554 hasPublicationYear "1970" @default.
• W2022088554 type Work @default.
• W2022088554 sameAs 2022088554 @default.
• W2022088554 citedByCount "44" @default.
• W2022088554 countsByYear W20220885542018 @default.
• W2022088554 countsByYear W20220885542021 @default.
• W2022088554 crossrefType "journal-article" @default.
• W2022088554 hasAuthorship W2022088554A5000698290 @default.
• W2022088554 hasAuthorship W2022088554A5035049323 @default.
• W2022088554 hasConcept C111919701 @default.
• W2022088554 hasConcept C121332964 @default.
• W2022088554 hasConcept C145148216 @default.
• W2022088554 hasConcept C155647269 @default.
• W2022088554 hasConcept C161790260 @default.
• W2022088554 hasConcept C178790620 @default.
• W2022088554 hasConcept C185592680 @default.
• W2022088554 hasConcept C191015642 @default.
• W2022088554 hasConcept C201194858 @default.
• W2022088554 hasConcept C2776254738 @default.
• W2022088554 hasConcept C2776640939 @default.
• W2022088554 hasConcept C2780263894 @default.
• W2022088554 hasConcept C40325409 @default.
• W2022088554 hasConcept C41008148 @default.
• W2022088554 hasConcept C512968161 @default.
• W2022088554 hasConcept C58364064 @default.
• W2022088554 hasConcept C62520636 @default.
• W2022088554 hasConcept C71240020 @default.
• W2022088554 hasConcept C75079739 @default.
• W2022088554 hasConcept C75473681 @default.
• W2022088554 hasConcept C81022585 @default.
• W2022088554 hasConceptScore W2022088554C111919701 @default.
• W2022088554 hasConceptScore W2022088554C121332964 @default.
• W2022088554 hasConceptScore W2022088554C145148216 @default.
• W2022088554 hasConceptScore W2022088554C155647269 @default.
• W2022088554 hasConceptScore W2022088554C161790260 @default.
• W2022088554 hasConceptScore W2022088554C178790620 @default.
• W2022088554 hasConceptScore W2022088554C185592680 @default.
• W2022088554 hasConceptScore W2022088554C191015642 @default.
• W2022088554 hasConceptScore W2022088554C201194858 @default.
• W2022088554 hasConceptScore W2022088554C2776254738 @default.
• W2022088554 hasConceptScore W2022088554C2776640939 @default.
• W2022088554 hasConceptScore W2022088554C2780263894 @default.
• W2022088554 hasConceptScore W2022088554C40325409 @default.
• W2022088554 hasConceptScore W2022088554C41008148 @default.
• W2022088554 hasConceptScore W2022088554C512968161 @default.
• W2022088554 hasConceptScore W2022088554C58364064 @default.
• W2022088554 hasConceptScore W2022088554C62520636 @default.
• W2022088554 hasConceptScore W2022088554C71240020 @default.
• W2022088554 hasConceptScore W2022088554C75079739 @default.
• W2022088554 hasConceptScore W2022088554C75473681 @default.
• W2022088554 hasConceptScore W2022088554C81022585 @default.
• W2022088554 hasIssue "12" @default.
• W2022088554 hasLocation W20220885541 @default.
• W2022088554 hasOpenAccess W2022088554 @default.
• W2022088554 hasPrimaryLocation W20220885541 @default.
• W2022088554 hasRelatedWork W1800965817 @default.
• W2022088554 hasRelatedWork W1964117855 @default.
• W2022088554 hasRelatedWork W2061983462 @default.
• W2022088554 hasRelatedWork W2074304097 @default.
• W2022088554 hasRelatedWork W2105609847 @default.
• W2022088554 hasRelatedWork W2332286683 @default.
• W2022088554 hasRelatedWork W4246414068 @default.
• W2022088554 hasRelatedWork W4296793620 @default.
• W2022088554 hasRelatedWork W4309953213 @default.
• W2022088554 hasRelatedWork W4386022506 @default.
• W2022088554 hasVolume "3" @default.
• W2022088554 isParatext "false" @default.
• W2022088554 isRetracted "false" @default.
• W2022088554 magId "2022088554" @default.

• next